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Acetone

Product: Acetone (alias: Dimethyl Ketone), IUPAC Name: Propan-2-one, English Name: Acetone, CAS No.: 67-64-1, Molecular Formula: C₃H₆O or CH₃COCH₃. It is a simple saturated aliphatic ketone and a bulk basic organic chemical raw material worldwide.

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Physical Properties

1. Appearance and Odor: Colorless, transparent, mobile liquid with a slightly sweet pungent odor.
2. Volatility and Boiling Point: Highly volatile; its boiling point (at standard atmospheric pressure) is generally between 56.0℃ and 56.6℃ (water bath heating is sufficient for atmospheric distillation).
3. Density and Water Solubility: Density 0.7899 g/cm³ (20℃), lighter than water; miscible with water, alcohols, ethers, chloroform, etc. in any proportion. It can dissolve oils, resins, rubber and cellulose, commonly known as "universal solvent" (critical for use as an extractant).
4. Hazardous Physical Parameters: Flash point -18℃ (extremely flammable); vapor is heavier than air (may spread along the ground).
5. UN Number: UN1090, Hazard Class 3, Packing Group Ⅱ.

Chemical Properties

Molecules contain carbonyl groups and feature active chemical properties:

1. Addition Reaction: It can undergo addition reactions with hydrogen, hydrogen cyanide and alcohols to produce isopropanol, cyanohydrin and ketal; ketals are often used to protect hydroxyl groups in organic synthesis.

2. Iodoform Reaction: Reacts with halogens under alkaline conditions to form iodoform, which is a characteristic reaction of methyl ketones.

3. Oxidation and Reduction: Not easily oxidized by weak oxidants at room temperature; cleavage occurs upon heating with strong oxidants to generate acetic acid and carbon dioxide; hydrogenation reduction yields isopropanol.

4. Condensation Reaction: Aldol condensation takes place in an alkaline environment to form important intermediates such as diacetone alcohol and isophorone.

Incompatible Substances: Strong oxidizing agents, concentrated nitric acid, chloroform and strong alkalis. Mixing storage and transportation are strictly prohibited.

Applications

Acetone is one of the world’s most widely used solvents due to its excellent solubility and rapid volatility. It is widely found in various daily necessities.

Acetone in the Chemical Industry

Acetone is mainly used as a solvent capable of dissolving many organic compounds. It serves as the starting material for multiple synthetic reactions in the chemical industry, such as the production of plastics, paints, varnishes, adhesives and nitrocellulose. Acetone is also an important intermediate for manufacturing chloroform and bromoacetone (tear gas). A key derivative of acetone is polymethyl methacrylate (PMMA), commonly known as acrylic glass or organic glass. It is applied in coatings, inks, adhesives, spray paints, man-made fibers and acetate fiber spinning; it is also used for equipment cleaning, extraction and dewaxing, as well as fast-drying thinners featuring fast volatilization and low residue.

It is used to synthesize bulk chemical products including bisphenol A, methyl methacrylate (monomer for organic glass), isophorone, diacetone alcohol, epoxy resin and polyisoprene rubber, acting as a critical node in the chemical industrial chain.

Acetone in Medical Applications

In the medical field, acetone is used for disinfection. In dentistry, acetone-containing solutions are applied to clean prepared dentin surfaces, root canals and dental restorations. In pharmaceuticals, it functions as an extractant (e.g., for vitamin production) and an auxiliary ingredient for disinfectants.

Acetone in Agriculture

In agriculture, acetone is used to manufacture pesticides. It acts as a carrier for active substances such as herbicides and insecticides.

Acetone in the Food Industry

Acetone can dissolve plant aromas and is therefore used to produce natural flavors in the food industry. It serves as an extraction solvent in food processing (e.g., caffeine extraction), but it must fully volatilize in the final products.

Other Application Fields of Acetone

Acetone is also used to produce methyl methacrylate and bisphenol A, both essential for manufacturing widely used plastics. Together with hydrogen peroxide, acetone is one of the basic raw materials for acetone peroxide (TATP), an explosive compound. To achieve more efficient fuel combustion, a small amount of acetone is added to gasoline or diesel in some countries at a ratio of 1:2000 to 1:5000.

In the photochemical production of PCBs, acetone is used for final degreasing of PCBs prior to soldering. In daily cosmetics, it is the main ingredient in nail polish remover to dissolve nail polish; it works as a thinner in coatings, a solvent for PVC adhesives, as well as a co-solvent and degreaser in cosmetics such as toners.

In laboratories, acetone is used as a solvent for equipment cleaning and experiments. In the textile industry, for example, acetone can remove oil stains and other contaminants from fabrics.

Storage and Transportation

Storage Requirements:

Strict temperature control is required. It must be stored in a cool, well-ventilated dedicated warehouse, away from fire and heat sources, and the warehouse temperature shall not exceed 30℃. Due to its high volatility, containers must be sealed and bulk stacking is not recommended. Note: Mix storage with oxidants, strong acids and strong bases is strictly prohibited (especially keep away from hydrogen peroxide).

Packaging and Materials:

Iron drums or plastic drums (anti-static required) are commonly used. Brown glass bottles (to prevent direct light exposure) can be selected for small daily storage. Ordinary rubber stoppers cannot be used as they will swell; PTFE or aluminum foil inner caps must be adopted.

Transportation Requirements (Hazardous Chemicals):

It belongs to Category 3.1 low flash point flammable liquid. Transport vehicles must be marked with warning signs for flammable liquids. Tank trucks shall be equipped with grounding chains to discharge static electricity. Operators shall wear anti-static clothing, and chemical fiber clothes are forbidden.

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